ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Phase diagrams including the compounds \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm UO}_2 - {\rm U}_4 {\rm O}_9 - {\rm U}_3 {\rm O}_8 - {\rm UO}_3 - {\rm UO}_2 {\rm F}_2 - {\rm UF}_3 - {\rm UF}_4 - {\rm UF}_{4,25} - {\rm UF}_{4\,5} - {\rm UF}_5 - {\rm UF}_6 $$\end{document} are calculated with the coordinates of temperature and partial pressure of O2, F2 and UF6, respectively. On the basis of these diagrams experimental equilibrium investigations are discussed as well as some technical fluorination reactions.
Notes:
Die Zustandsgebiete der Verbindungen \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm UO}_2 - {\rm U}_4 {\rm O}_9 - {\rm U}_3 {\rm O}_8 - {\rm UO}_3 - {\rm UO}_2 {\rm F}_2 - {\rm UF}_3 - {\rm UF}_4 - {\rm UF}_{4 \cdot 25} - {\rm UF}_{4 \cdot 5} - {\rm UF}_5 - {\rm UF}_6 $$\end{document} werden in Abhängigkeit von der Temperatur und den Partialdrucken O2, F2 bzw. UF6 berechnet und graphisch dargestellt. An Hand dieser Diagramme werden experimentelle Gleichgewichtsuntersuchungen und technische Fluorierungsreaktionen erörtert.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19693700110
