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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 394 (1972), S. 279-289 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The molar electrical conductivities and excess conductivities of the molten mixtures CaCl2-MeCl (Me = Li, Na, K, Rb, Cs); NaCl-MeCl2 (Me = Ca, Sr, Ba) and the relative cation mobilities of the molten mixtures CaCl2-(LiCl, RbCl) are calculated. The values are obtained from the experimental determination of the densities, specific electrical conductivities, activities and transference numbers, published in previous works. The possible structure of these charge-unsymmetrical melts are discussed from the obtained results.
    Notes: Aus den experimentell bestimmten elektrischen Leitfähigkeiten, Dichten, Aktivitäten und Überführungszahlen werden die molaren elektrischen Leitfähigkeiten, Exzeßleitfähigkeiten der geschmolzenen Mischungen CaCl2-MeCl (Me = Li, Na, K, Rb, Cs); NaCl-MeCl2 (Me = Ca, Sr, Ba) und die relativen Kationenbeweglichkeiten in den geschmolzenen Mischungen CaCl2-(LiCl, RbCl) berechnet. Aus den erhaltenen Ergebnissen werden Aussagen über die mögliche Struktur dieser ladungsunsymmetrischen Schmelzen abgeleitet und diskutiert.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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