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  • 1
    Electronic Resource
    Electronic Resource
    Abnormal viscosimetric behavior of homopolymers in mixed solvents and preferential solvation (1976)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 309-315 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: It is shown that the applicability of the Stockmayer-Fixman-Burchard plot is much more limited in the case of solvent-precipitant mixtures than in the case of pure solvents. The observed deviations can be explained by taking into account the variation of preferential solvation as a function of the molecular weight of the polymer. More precisely the average density of the segments in the region occupied by the coiled molecule seems to be the parameter governing both changes in viscosity and in preferential solvation.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1976.180140210
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