ISSN:
1612-1112
Keywords:
Column liquid chromatography
;
Un-sulphated and sulphated surfactants
;
Oligoethyleneglycol nonylphenyl ethers
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Retention behaviour of un-sulphated and sulphated, oligoethyleneglycol nonylphenyl ether, anionic surfactants was investigated in normal-phase LC systems with chemically bonded amino stationary phase in organic mobile phases containing water and cetyl trimethylammonium bromide (CTAB). Addition of water to the mobile phase improves efficiency of separation and linearity of the dependences of logk′ versus number of oxyethylene units in the sulphated oligomers, so that it is possible to describe simultaneous effects of this number and of the concentration of CTAB on retention by a simple equation. In this system, it is possible to separate lower sulphated and un-sulphated oligomers in a single run in 10–15 min under isocratic conditions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02290288
