ISSN:
1089-7550
Source:
AIP Digital Archive
Topics:
Physics
Notes:
Nonhydrogenated diamondlike carbon films prepared at a substrate temperature (ST) of 100, 300, and 500 °C by the laser ablation of graphite on a single-crystal silicon substrate have been characterized by scanning tunneling microscopy for the surface structure and Raman spectroscopy for the microstructure. Distorted pentagonal and hexagonal rings are observed on the surface of the film grown at 100 °C while only hexagonal rings are observable for the one grown at 500 °C. The rise in ST is found to increase the surface roughness. To assign the various coexisting carbonaceous species formed at different growth temperatures and to check their thermal stability, heat treatment was performed at up to 1300 °C in vacuum and 600 °C in air. The changes occurring on heat treatment in vacuum in these films around 600 °C have been correlated with the release of defects from the threefold network. Likewise, 950 °C temperature has been associated with the conversion of disordered tetrahedral bonding to a distorted trigonal one. The heat treatment in air shows that the microstructure induced due to lower ST is thermally more stable. © 1996 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.361081
