ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
In an attempt to study the specific influence of cross-linking on the α relaxation in polymer networks, a series of model heterocyclic polymer networks (HPN) with well-defined cross-link densities and constant concentration of dipolar units were studied. Model HPN systems were prepared by simultaneous trimerization of 1,6-hexamethylene diisocyanate (HMDI) and hexyl isocyanate (HI). These HPN systems were characterized by dielectric relaxation spectroscopy in the 10−1 Hz〈F〈105 Hz frequency range and in the 123 K〈T〈493 K temperature interval. The α relaxation in these systems depends on network density and shifts toward higher temperatures as the cross-link density increases for high HMDI/HI ratios. Discussion of the α-relaxation shape in light of recent models indicates that segmental motions above the glass transition systematically experience a growing hindrance with increasing degree of cross-linking. Description of the temperature dependence of relaxation times according to the strong–fragile scheme clearly shows that fragility increases as polymer network develops. © 2000 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.481809
