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Digitale Medien

Functionalization of an amorphous ethylene-propylene copolymer by free radical initiated grafting of unsaturated molecules (1984)

De Vito, G. ; Lanzetta, N. ; Maglio, G. ; [weitere]

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1335-1347

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Details

ISSN: 0360-6376

Schlagwort(e): Physics ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Functionalization of an amorphous ethylene-propylene copolymer, EPM, has been performed by means of homogeneous grafting reactions of unsaturated molecules such as dibutylmaleate, diethylfumarate, itaconic anhydride, and maleic anhydride, initiated by free radicals. Dicumylperoxide and dibenzoylperoxide have been used as a free radical source and their efficiency has been compared. A different reactivity of the unsaturated molecules has been evidenced. The influence of the nature of the solvent on the functionalization degree has been investigated, revealing a noticeable effect of the solvent either on the amounts of grafted molecules or on the secondary reactions which lead to partial degradation of the functionalized EPM chains.

Zusätzliches Material: 8 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1984.170220614

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