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Digitale Medien

Reactions of trichloro(cyclopentadienyl)titanium(IV) with 1,5-diarylthiocarbazones (1987)

Singh, Yogendra ; Sharan, Ram ; Kapoor, Ramesh N.

Springer

Transition metal chemistry 12 (1987), S. 335-338

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Details

ISSN: 1572-901X

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Summary The synthesis and characterization of the complexes from the reactions of trichloro(cyclopentadienyl)titanium(IV) with 1,5-diarylthiocarbazones (aryl=phenyl,o-tolyl,o-chlorophenyl,p-tolyl,p-chlorophenyl, or 3,5-dimethylphenyl) are reported. They are of the types CpTi(HDz)Cl2 and CpTi(HDz)2Cl (Cp=cyclopentadienyl, HDz−=the mono-anion of a 1,5-diarylthiocarbazone, H2Dz). The compounds are nonelectrolytes in dimethylformamide (DMF). In solid state, the far i.r. spectra of CpTi(HDz)Cl2 indicate the complexes to be dimeric, involving Cl-bridges.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF01024027

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