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Digitale Medien

The removal of DF (v=3 and 4) by H and D atoms (1985)

Bott, J. F.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 83 (1985), S. 5567-5572

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Details

ISSN: 1089-7690

Quelle: AIP Digital Archive

Thema: Physik , Chemie und Pharmazie

Notizen: The deactivation rate coefficients for the removal of DF (v=3) and DF (v=4) by H and D atoms have been measured at 295 K by the technique of laser-induced fluorescence in a discharge flow-tube apparatus. The rate coefficients were found to increase dramatically with vibrational level v. Data obtained for the removal of DF (v=4) in the presence of H atoms have been used to infer a rate coefficient of (4.5±2)×1011 cm3/mol s for the reaction H+DF (v=4)→HD+F. This is in good agreement with a value calculated from the equilibrium constant and a previous measurement of the F+HD rate coefficient obtained by Berry.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1063/1.449679

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