Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
83 (1985), S. 5567-5572
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The deactivation rate coefficients for the removal of DF (v=3) and DF (v=4) by H and D atoms have been measured at 295 K by the technique of laser-induced fluorescence in a discharge flow-tube apparatus. The rate coefficients were found to increase dramatically with vibrational level v. Data obtained for the removal of DF (v=4) in the presence of H atoms have been used to infer a rate coefficient of (4.5±2)×1011 cm3/mol s for the reaction H+DF (v=4)→HD+F. This is in good agreement with a value calculated from the equilibrium constant and a previous measurement of the F+HD rate coefficient obtained by Berry.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.449679
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