ISSN:
0935-6304
Keywords:
Supercritical-Fluid Extraction (SFE)
;
Supercritical-Fluid Chromatography (SFC)
;
Recovery
;
Optimization
;
Retention Data
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The possibility of using supercritical-fluid chromatographic retention data for examining the effects of operational parameters, such as pressure and flow rate, on the extraction characteristics in supercritical-fluid extraction (SFE) was investigated. A model was derived for calculating the extraction efficiency in SFE from retention data and peak shapes measured in supercritical-fluid chromatography (SFC). By performing the SFC experiments at the same pressure and temperature as the SFE extractions using the SFE extraction cell as the SFC column, an accurate prediction of extraction efficiencies could be made. Finally, the effects of matrix composition and analyte concentration on extraction efficiency were studied.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240180805
