ISSN:
0935-6304
Keywords:
Liquid chromatography
;
reversed phase
;
prototypical substances
;
retention parameter model
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
---A set of four prototypical substances (naphthalene, acetanilide, phenol, and benzonitrile) is selected from 26 different analytes used by Seibert and Poole for characterization of the retention behavior of 20 liquid chromatographic systems of a C18 reversed phase with methanol/water and acetonitrile/water as mobile phases. Retention data of 22 different analytes can be calculated from the retention data of the set of prototypical substances with a mean standard deviation of 5.4%. Two phase system maps similar to that suggested by Poole et al. are provided for an octadecylsiloxane-bonded silica sorbent with methanol and acetonitrile as cosolvents with water.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
