ISSN:
0935-6304
Keywords:
Carboxymethyl derivatives of amines
;
dodecyl-L-hydroxyproline
;
chelate ring
;
chemiluminescence
;
ruthenium complex
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
---Carboxymethyl derivatives of amines containing a chiral α-carbon were separated into enantiomers by high-performance liquid chromatography using octadecylsilanized silica gel coated with N-n-dodecyl-L-hydroxyproline as the stationary phase and an aqueous solution containing copper(II) as the mobile phase. Detection was by post-column reaction involving derivatization to tertiary amine and chemiluminescence reaction of ruthenium bipyridine complex.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource