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Line widths in the pure rotational Raman spectra of nitrogen, oxygen and hydrogen broadened by foreign gases (1988)

Edwards, H. G. M. ; Long, D. A. ; Webb, S. W.

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 19 (1988), S. 457-461

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ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Broadening coefficients, σp, have been determined for the pure rotational Raman lines of nitrogen and oxygen, perturbed by hydrogen, helium and methane, and of hydrogen broadened by helium, argon, nitrogen and carbon monoxide, over the pressure range 2-100 bar with a host gas partial pressure of 1 bar. The results are summarized below:The broadening coefficients are discussed in relation to the dipole, quadrupole and octopole moments and the polarizabilities of the perturbing species.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250190705

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