ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Measurements of the low-frequency Raman spectra (LFRS) (below 100 cm-1) of poly(methyl methacrylates) in solution are reported. The reduced intensity exhibits a power law dependence on the frequency at any concentration and at any conversion rate of the polymerization reaction. Even monomeric liquids such as toluene and methyl methacrylate show such a power law behaviour. The results are compared with recent theories on low-frequency Raman scattering from fractal structures and suggest that a more careful interpretation of LFRS is needed.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250250504