ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Ultra-fast pulsed laser measurements in the time domain have several advantages over traditional frequency-domain spectroscopy. For example, very low frequency modes are more easily probed, fluorescent samples can be studied and vibrational modes that are directly coupled to chemical reactions are revealed. This study demonstrated some of these advantages using heme protein samples. Low-frequency modes are observed in deoxymyoglobin (deoxyMb), fluorescence rejection is demonstrated with metMb and product-state vibrational coherence is revealed with MbNO.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250260708
