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Electron-impact induced fragmentation of 2-substituted 2H-cyclopenta[D]pyridazines (1969)

Forkey, David M.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 2 (1969), S. 309-315

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The mass spectra of the non-benzenoid aromatic heterocycles 2H- and 2-methyl-2H-cyclopenta[d]pyridazine and several deuterated analogs have been analyzed. The majority of the nitrogen lost from these heterocycles occurs as HCN OR H2CN. The deuterium labeling suggests a rearrangement of the molecular ion prior to fragmentation.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210020309

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