ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The pyrolysis of some perfluoroalkylene-linked aromatic and heteroaromatic polymer precursors and a poly(1,3-phenylenehexafluorotrimethylene) has been studied using a combined pyrolysis-gas chromatographic-mass spectrometric method. Whereas the electron-impact induced fragmentations of the polymer precursors are almost exclusively controlled by cleavage β to the aromatic or heteroaromatic ring, thermolysis of these compounds yields products whose formation is consistent with the occurrence of primary cleavage processes that are not confined β to the ring.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210070103