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Concerning the Beckmann rearrangement of aryl heteryl ketoxime ions (1982)

Grützmacher, Hans-fr. ; Römer, Christian

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 17 (1982), S. 318-320

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The possible Beckmann rearrangement of aryl heteryl ketoxime ions has been investigated by studies on the 70 eV mass spectra, metastable ion spectra and collision induced dissociation spectra of pairs of isomeric ketoximes and corresponding amides. Aryl cycloalkyl ketoximes were also studied, and the molecular ions of these and the corresponding amides showed no evidence of interconversion. The introduction of the heterocyclic moieties made little change to this situation although some novel rearrangements were observed.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210170706

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