ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
A new freezing process for the desalination of seawater is being developed which utilizes a unique way of upgrading heat energy where there is no gas phase involved. This method takes advantage of the abnormal melting point curve of water. Water melts at a lower temperature under a higher applied pressure (that is, (dp/dT) melting 〈 0), while an ordinary substance melts at a higher temperature under a higher applied pressure (that is, (dP/dT) melting 〉 0). Due to this differnce a substance which melts at a temperature lower than the freezing point of an aqueous solution may melt at a temperature higher than the melting point of water at a sufficiently high pressure.Thus, a suitably selected working medium can be used to form a cyclic auxiliary system which can be incorporated with the main system to: remove the heat of crystallization of water in the partial freezing of an aqueous solution by melting the working medium at a low pressure, and to supply the heat for melting the ice by solidifying the working medium at a sufficiently high pressure.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690130110