ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
The dispersion equation for a single, nonreacting, nonadsorbing species is derived for incompressible, laminar flow in anisotropic porous media. Direct integration of the appropriate differential equations gives rise to a dispersion vector ψi and a tortuosity vector τi, both of which must be evaluated experimentally. For the dispersion vector, this is conveniently done by representing ψi in terms of the velocity and gradients of the velocity and concentration. The experimental determination of τi is not straightforward except for the case of pure diffusion. The analysis yields a result which contains all the features of previously presented dispersion equations without making any assumptions as to the nature of the flow, that is, bypassing, cell mixing, etc., except that it be laminar. Attacking the dispersion problem in terms of the differential diffusion equation provides a rational basis for the correlation of experimental data and illustrates the connection between the microscopic and macroscopic equations.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690130308