ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
Thermodynamic properties pertaining to phase equilibria in the binary-fluid hydrate systems, methylene chloride-water and chloroform-water, and the ternary hydrate system, methylene chloride-chloroform-water, were measured. Total vapor pressure data were recorded as a function of temperature over a range of -3 to + 10°C. Quadruple locus measurements of the ternary four-phase equilibrium, L1-L2-H-G, and isobaric studies of the ternary system chloroform-methylene chloride-water, support the existence of a solid solution hydrate between methylene chloride and chloroform. The addition of the nonhydrate former, hexane, to the methylene chloride-water system lowered the isobaric critical decomposition temperature of the hydrate.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690150221
