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Electrooxidation of urea at the ruthenium titanium oxide electrode (1986)

Wright, J. C. ; Michaels, A. S. ; Appleby, A. J.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 32 (1986), S. 1450-1458

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ISSN: 0001-1541

Keywords: Chemistry ; Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: Urea adsorbs on the ruthenium titanium oxide electrode, depressing the observed current. For artificial kidney dialysate concentrations of urea and NaCl (0.50 kg/m3 and 100 mol/m3, respectively), the major electrolysis products are N2, CO2, O2, and H2, and the reaction mechanism is solution oxidation of urea by anodically generated active chlorine. A nitrogen-yielding direct electrode reaction is observed at high urea concentration (30 kg/m3) and low NaCl concentration (10-100 mol/m3).

Additional Material: 12 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/aic.690320906

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