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Digitale Medien

Thermodynamics of hydrogen-bonded molecules: The associated perturbed anisotropic chain theory (1986)

Ikonomou, G. D. ; Donohue, M. D.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 32 (1986), S. 1716-1725

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Details

ISSN: 0001-1541

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung

Notizen: The perturbed anisotropic chain theory (PACT) developed by Vimalchand and Donohue has been generalized to treat pure fluids that associate through hydrogen bonding, as well as mixtures of one associating component and several diluents. Using an approach similar to that of Heidemann and Prausnitz, a closed-form equation of state has been derived. It is applicable to simple as well as complex molecules at both gas and liquidlike densities and takes into account dipole and/or quadrupole moments. Molecular parameters were obtained by fitting the equation to experimental liquid density and vapor pressure data.

Zusätzliches Material: 9 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/aic.690321015

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