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Digitale Medien

Free radical kinetics in irradiated ethyl cellulose as determined by electron spin resonance measurements (1962)

Loy, B. R.

Stamford, Conn. [u.a.] : Wiley-Blackwell

Polymer Engineering and Science 2 (1962), S. 157-160

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Details

ISSN: 0032-3888

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Maschinenbau , Physik

Notizen: Electron spin resonance techniques are used to investigate the structure and decay of radicals produced in irradiated ethyl cellulose. Approximately 99% of the radicals trapped at liquid nitrogen temperature appear to be - C2H4. radicals. These decay immeasurably fast at room temperature. The relatively stable doublet that remains is believed to be due to the CH—O radical. The kinetics of the doublet decay are studied as a function of temperature and dose. The data may be interpreted as resulting from simultaneous first and second order processes at lower doses and from a second order process at higher doses.

Zusätzliches Material: 10 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pen.760020227

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