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Digitale Medien

High speed electron spin resonance techniques applied to polymer fracture (1979)

Britt, A. D. ; Moniz, W. B. ; Chingas, G. C.

Stamford, Conn. [u.a.] : Wiley-Blackwell

Polymer Engineering and Science 19 (1979), S. 112-113

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Details

ISSN: 0032-3888

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Maschinenbau , Physik

Notizen: Mechanical fracture of nylon 6 produces free radicals as a direct result of bond-breaking; these initial free radicals rapidly decay into secondary free radicals at room temperature. Aromatic nitro-compounds react with the initial, but not the secondary, free radicals. The rate of reaction is sufficiently fast to compete with the usual initial radical decay process, even at room temperature. Considerations involved in applying high speed (microsecond) electron spin resonance techniques are discussed.

Zusätzliches Material: 1 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pen.760190211

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