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Digitale Medien

An improved concept in solubility parameter theory applied in amorphous polymers. I. Poly(ethyl methacrylate) (1979)

Karim, K. A. ; Bonner, D. C.

Stamford, Conn. [u.a.] : Wiley-Blackwell

Polymer Engineering and Science 19 (1979), S. 1174-1177

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Details

ISSN: 0032-3888

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Maschinenbau , Physik

Notizen: Gas-liquid chromatography has been used to estimate thermodynamic parameters of a variety of aromatic and aliphatic solvents at infinite dilution in poly(ethyl methacrylate). Heats of solution, Flory-Huggins interaction parameters, and specific interaction parameters were calculated from specific retention volumes. Comparative interpretation of these thermodynamic quantities has led to the establishment of a solvent selectivity scale for poly(ethyl methacrylate). Limitations of the threedimensional solubility parameter theory on the systems tested here are demonstrated. A significantly improved concept is developed and tested.

Zusätzliches Material: 4 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pen.760191608

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