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Digitale Medien

Kinetic model and thermal properties of a thermally cured thermosetting polycarbonate (1994)

Delgado, R. ; McNeill, D. M. ; Hawley, M. C. ; [weitere]

Stamford, Conn. [u.a.] : Wiley-Blackwell

Polymer Engineering and Science 34 (1994), S. 734-741

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Details

ISSN: 0032-3888

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Maschinenbau , Physik

Notizen: Diethylene gycol bis(allyl carbonate) is widely used for the production of optical plastic for lenses, safety glasses and guards, watch crystal, and instrument windows. The monomer polymerizes via a free radical mechanism using benzoyl peroxide as an initiator to form a thermosetting polycarbonate. This polymerization process involves a long cure cycle at temperature below 100°C. Differential scanning calorimetry (DSC) and rheometric dynamic testing are used to characterize the thermal and kinetic properties. These properties include the heat of reaction, activation energy, rate constants of polymerization, and time and extent of cure at gelation.

Zusätzliches Material: 12 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pen.760340906

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