ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Organometalphosphine-substituted Transition Metal Complexes, XXIV. Organoelement(IVb)-phosphine Derivatives of OctacarbonyldicobaltOctacarbonyldicobalt (1) reacts with (t-C4H9)3P (2), (t-C4H9)2PH (3), [(CH3)3Si]3P (4),[(CH3)3Ge]3P (5) [(CH3)3Sn]3P (6) and (t-C4H9)2[(CH3)3Si]P (7) with displacement of two CO ligands and formation of corresponding hexacarbonyldi(organoelement)IVb)-phosphine)-cobalt complexes. The vibrational and NMR spectra of the new compounds are discussed.
Notes:
Octacarbonyldicobalt (1) reagiert mit (t-C4H9)3P (2), (t-C4H9)2PH (3), [(CH3)3Si]3P (4), [(CH3)3 Ge]3P (5), [(CH3)3Sn]3P (6) und (t-C4H9)2[(CH3)3Si]P (7) unter Abspaltung von zwei CO-Liganden und Bildung entsprechender Hexacarbonyldi(organoelement(IVb)-phosphan)-cobalt-Komplexe. Die Schwingungs- und Kernresonanzspektren der neuen Verbindungen werden diskutiert.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19791120529
