ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Contributions to the Chemistry of Boron, 142. Some Substitution Reactions of 1,3-Dimethyl-1,3,2-diazaborolidines and the Anomalous Dimerisation of its 2-Fluoro DerivativeThe transamination of B[N(CH3)2]3 with α,ω-dimethylalkylenediamines proceeds via the bridged species 2 and 3. These react with boron halides to yield 2-halo-diazaborolidines. The 2-fluoro derivative 6 has been obtained from fluorination of the 2-methylthio compound with SbF3. 6 dimerizes in an anomalous fashion yielding a fluxional tricyclic species.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19841170727