ISSN:
0009-2940
Keywords:
Lanthanide alkoxides
;
Tritox ligand
;
Neodymium
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Soluble Lanthanide Alkoxides with Low Coordination Numbers at the Metal AtomNd[N(SiMe3)2]3(thf)2 (1) reacts with tBu3COH (2) to give the monomeric lanthanide alkoxide (tritox)3Nd(thf) (3). The chloro-bridged dimer [(tritox)2Nd(μ-Cl)thf]2 (6) is obtained by treatment of NdCl3(thf)2 (4) with LiOCtBu3 (5). The structure of 6 has been determined by X-ray crystallography.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240530