ISSN:
0009-2940
Keywords:
1,8-Diaminonaphthalenes, X-ray structure analysis of, conformational barriers of, dynamic behavior of
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The title compounds 2 and 3 have been synthesized from 1,8-diaminonaphthalene. The molecular structure of 2 has been determined by X-ray structure analysis and is discussed with regard to the arrangement of the peri-diphenylamino substituents in the crystalline state and the steric strain in the molecule. NMR studies of 3 reveal two conformational processes. Their nature is discussed and barriers are reported.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250327