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Ein einfacher Weg zu Silicium in oktaedrischer Sauerstoffkoordination (1994)

Königstein, Karsten ; Jansen, Martin

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 127 (1994), S. 1213-1218

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ISSN: 0009-2940

Keywords: Silicon ; Octahedral oxygen coordination ; Phosphorus ; NMR, 1H MAS ; NMR, 29Si MAS ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A Simple Route to Silicon in Octahedral Oxygen CoordinationSyntheses and crystal structures of three new compounds Rb2SiP4O13 (1), Cs2H2Si(P2O7)2 (2), and BaH2Si(P2O7)2 (3) containing silicon in an octahedral oxygen coordination are reported. The structures have been determined by X-ray structure analyses. All three compounds are constituted of silicophosphate polyanions. The NMR chemical shifts of silicon and hydrogen are measured.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19941270706

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