ISSN:
0009-2940
Keywords:
Trifluoromethyl vinyl sulfide
;
Gas-phase structure
;
Electron diffraction
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The geometric structure of trifluoromethyl vinyl sulfide, CF3SC(H)=CH2, was determined by gas electron diffraction and ab initio calculations (HF/3-21G* and MP2/6-31G*). A single conformer with a dihedral angle φ(C=C-S-C) = 129(4)° is present. The conformational properties are compared to those of the parent compound, CH3SC(H)=CH2, and of the perfluorinated species CF3SC(F)=CF2.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971300122