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Silver Chloroacetate: Crystal Structure and Thermal Polymerization Mechanism (1997)

Epple, Matthias ; Kirschnick, Holger

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 291-294

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ISSN: 0009-2940

Keywords: Halogenoacetates ; Silver salts ; Solid-state reactions ; Polymerization ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The structure of silver chloroacetate was determined by single-crystal X-ray structure analysis. This represents the first salt of a monohalogenoacetic acid with a monovalent metal whose structure was determined with high precision. The salt undergoes a thermally induced solid-state polymerization to polyglycolide under elimination of silver chloride. A probable mechanism for a structure-determined reaction in the solid state is discussed.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19971300224

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