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  • 1
    Electronic Resource
    Electronic Resource
    Dynamic Behavior of Anionic Binuclear Helicate- and meso-Helicate-Type Coordination Compounds (1997)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 615-619 
    Details
    ISSN: 0009-2940
    Keywords: Self-assembly ; NMR spectroscopy ; Titanium ; Catechol ligands ; Helical structures ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The racemization/symmetrization of helicate- or meso-helicate-type dinuclear titanium(IV) complexes Mn[(ligand)3Ti2] (n = 4: M = Li, Na, K, Cs; n = 2: M = Ca, Sr), which are formed by metal-directed self-assembly of alkyl-bridged bis(catecholate) ligands in the presence of basic alkali-metal or alkaline-earth metal salts, can be monitored by dynamic NMR spectroscopy. The free-energy barrier (ΔG
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19971300512
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