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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 35-39 
    ISSN: 1434-1948
    Keywords: Fluorescent sensors ; Molecular recognition ; Charge transfer excited states ; Metal complexes ; pH Sensors ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The fluorescent emission of the N,N-dimethylaniline fragment of the tetramine system 3varies with pH, displaying a maximum of the fluorescent intensity, IF, at pH = 5. Binding of transition metals (CuII, NiII) induces fluorescence quenching and modifies the IF vs. pH profile, giving rise to an OFF-ON-OFF type of sensor. The [ZnII(3)]2+complex recognises carboxylate anions, both aliphatic and aromatic. Recognition is signalled via fluorescence quenching only for aromatic carboxylates.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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