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2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene as an η6-Ligand in Transition Metal Complexes (1999)

Binger, Paul ; Stutzmann, Stefanie ; Stannek, Jörg ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 83-86

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ISSN: 1434-1948

Keywords: 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene ; η6-Triphosphabenzene transition metal complexes ; Displacement reactions ; Phosphorus heterocycles ; Arene complexes ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The η6-1,3,5-triphosphabenzene transition metal complexes 12a,b, 14, and 16 have been synthesized for the first time by the displacement of η6-arene ligands (toluene, benzene and naphthalene) with 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene (9). The new complexes have been fully characterized by a combination of elemental analysis, mass spectrometry, and 1H-, 13C- and 31 P-NMR spectroscopy.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

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