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Aldehyde Complexes of Zinc Halides (1999)

Müller, Bodo ; Vahrenkamp, Heinrich

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 129-135

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ISSN: 1434-1948

Keywords: Zinc ; Aldehyde ligands ; Halide ligands ; Structural chemistry ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Aldehyde complexes of the zinc halides were obtained by treating ZnCl2, ZnBr2, and ZnI2 under anhydrous conditions with large excesses of benzaldehyde and various substituted benzaldehydes. Their constitutions were determined by a total of 12 X-ray structure analyses. Three product types were found: ZnHal2(aldehyde)2 (A), [ZnHal2(aldehyde)]∞ (B), and [Zn(aldehyde)6] [Zn2Hal6] (C). All three dissolve readily in the corresponding aldehyde or in polar nonprotic solvents indicating the presence of solvated zinc species in solution.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

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