ISSN:
1434-1948
Keywords:
Phthalocyanines
;
Rhenium
;
Nitrido(octa-n-alkylphthalocyaninato)rhenium compounds
;
Nucleophilic additions
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reactions of nitrido(tetra-tert-butylphthalocyaninato)rhenium (1) with boron tribromide leading to (tBu4Pc)ReNBBr3 (4) and with acetone to give the imido complex (tBu4Pc)Re[NC(CH3)2CH2C(O)CH3]OH (2b) and its μ-oxo dimer 3 are reported. Starting from the corresponding 4,5-di-n-alkylphthalonitriles and ammonium perrhenate four soluble nitrido(octa-n-alkylphthalocyaninato)rhenium complexes 5-8 were synthesized. Nitrido(octa-n-pentylphthalocyaninato)rhenium (6) was treated with boron tribromide to afford [(C5H11)8Pc]ReNBBr3 (9).
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
