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Standard Molar Enthalpies of Formation of Mg and Ca Alkoxides (2000)

Barreira, Teresa ; Leal, João Paulo

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 2000 (2000), S. 987-991

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ISSN: 1434-1948

Keywords: Thermochemistry ; Alkaline-Earth Alkoxides ; Enthalpy of Formation ; Calcium ; Magnesium ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The enthalpies of formation of some alkaline-earth alkoxides were determined by reaction-solution calorimetry (ΔfHo[Mg(OMe)2] = -792.6±1.2 kJ/mol; ΔfHo[Mg(OEt)2] = -847.9±2.7 kJ/mol; ΔfHo[Ca(OMe)2] = -890.8±6.4 kJ/mol; ΔfHo[Ca(OEt)2] = -924.5±2.6 kJ/mol; ΔfHo[Ca(OBu)2] =-989.8±5.4 kJ/mol) and allowed us to extend a previously developed model for predicting the enthalpies of formation of Be, Sr and Ba alkoxides.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

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