ISSN:
1434-193X
Schlagwort(e):
Radical reactions
;
Glycolic acid
;
Asymmetric synthesis
;
Annulation
;
Selenium
;
Chemistry
;
General Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
-The stereoselective preparation of 1-hydroxycyclopentanecarboxylic acid derivatives is reported. The key reaction is either a radical cyclization or a radical annulation mediated by the transfer of a phenylseleno group. The radical precursors are easily synthesized by two consecutive enolate alkylations. Excellent stereochemical control for the quaternary C(1) stereogenic center has been achieved.
Zusätzliches Material:
2 Ill.
Materialart:
Digitale Medien