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α-Oxosulfone, 5. Reaktionen eines cyclischen α-Ketosulfons (1983)

Schank, Kurt ; Werner, Frank

Weinheim : Wiley-Blackwell

Liebigs Annalen 1983 (1983), S. 1739-1743

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ISSN: 0170-2041

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: α-Oxosulfones, 5. - reactions of a Cyclic α-Ketosulfone5,5-Dioxo-6H-dibenzo[b,d]thiopyran-6-one (4) as the first „real α-ketosulfone“ was isolated, and some of its reactions were studied. Apparently, 4 represents formally a border case between a thioester S,S-dioxide and an „α-ketosulfone“.

Notes: Als erstes „wirkliches α-Ketosulfon“ wurde 5,5-Dioxo-6H-dibenzo[b,d]-thiopyran-6-on (4) isoliert. Beim Studium einiger seiner Reaktionen zeigte sich, daß 4 formal einen Grenzfall zwischen einem Carbonsäurethioester-S,S-dioxid und einem „α-Ketosulfon“ darstellt.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.198319831009

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