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Radikalinduzierte Reduktion von α,β-ungesättigten Steroidketonen mit Tributylzinnhydrid (1983)

Laurent, Henry ; Esperling, Peter ; Baude, Günter

Weinheim : Wiley-Blackwell

Liebigs Annalen 1983 (1983), S. 1996-1999

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ISSN: 0170-2041

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Radical-induced Reduction of α,β-Unsaturated Steroid Ketones with Tributyltin HydrideConjugated steroid ketones are reduced stereoselectively with tributyltin hydride in the presence of azobisisobutyronitrile as radical initiator to give the corresponding saturated ketones in high yields.

Notes: Konjugierte Steroidketone werden mit Tributylzinnhydrid in Gegenwart des Radikalbildners Azobisisobutyronitril stereoselektiv und in hohen Ausbeuten zu den gesättigten Ketonen reduziert.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.198319831114

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