ISSN:
0170-2041
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Stereoselective Synthesis of Alcohols, XVII. - Stereoselective Synthesis of Optically Active α-Multistriatin, the Attractant of the Smaller European Elm Bark Beetle, Scolytus MultistriatusChiral epoxyalcohol (ent-7) and the diethylalkynylalane 9 gave diastereoselectively the diol 10. This was transformed by standard operations into the alcohol 13 and ultimately into (+)-α-multistriatin (ent-1) of 83% isomeric purity.
Notes:
Aus dem chiralen Epoxyalkohol (ent-7) und dem Diethylalkinylalan 9 erhielt man diastereoselektiv das Diol 10. Daraus wurden durch Standardoperationen der Alkohol 13 und weiter (+)-α-Multistriatin (ent-1) von 83% Isomerenreinheit dargestellt.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.198419840612