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Stereocontrolled Synthesis of all Four Steroisomers of Verrucarinolactone from (R)-2,3-O-Isopropylidene-Glyceraldehyde (1986)

Mulzer, Johann ; Salimi, Nabiollah

Weinheim : Wiley-Blackwell

Liebigs Annalen 1986 (1986), S. 1172-1178

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ISSN: 0170-2041

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Stereokontrollierte Synthese aller vier Stereoisomeren des Verrucarinsäurelactons aus (R)-2,3-O-IsopropylidenglycerinaldehydEine praktikable Synthese von (+)- und (-)- Verrucarinsäurelacton (2) sowie Epiverrucarinsäurelacton (1) aus (R)-2,3-O-Isopropylidenglycerinaldehyd wird beschrieben. Als Schlüsselzwischenstufen dienen die Verbindungen 3a/b.

Notes: A practical synthesis of (+)- and (-)-verrucarinolactone (2) and epiverrucarinolactone (1) from (R)-2,3-O-isopropylideneglyceraldehyde via the key intermediates 3a/b is described.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.198619860705

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