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Herstellung von 6,14-Ethenomorphinan-Derivaten (1993)

Marton, János ; Szabó, Zoltán ; Hosztafi, Sándor

Weinheim : Wiley-Blackwell

Liebigs Annalen 1993 (1993), S. 915-919

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ISSN: 0170-2041

Keywords: Buprenorphine ; Diprenorphine ; Rotamers, N-CHO ; Morphinane derivatives ; Alkaloids ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Preparation of 6,14-Ethenomorphinane DerivativesBuprenorphine (5j) and diprenorphine (5k) were synthesized from N-formyl-northebaine (1c) and N-benzyl-northebaine (1d) via new intermediates. N-cyclopropylmethyl-dihydronorthevinone 3d is a suitable compound for the synthesis of both 5j and 5k. We carried out detailed 1H- and 13C-NMR analysis of the new compounds.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.1993199301144

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