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  • 1
    ISSN: 0268-2605
    Keywords: siloxanyl-modified ; carbohydrate ; surfactant ; wetting behaviour ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The siloxanyl-modified carbohydrate surfactants investigated consist of the four structural elements: (1) siloxanyl moiety; (2) spacer; (3) carbohydrate unit; and (4) modifying element. By static surface tension (γsν  -  γsβ α) measurements the contact angles of the aqueous surfactant solutions above the critical micelle formation concentration (cmc) on nonpolar perfluorinated surfaces (FEP® plate) were determined. Although the siloxanyl units were found to have a high capacity to level out the interfacial properties, both surface tension and wetting tension react independently to defined changes in the chemical structure of the surfactant molecules. The results of spreading experiments on polyproylene show good correlation with the dependences found by wetting meaurements. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
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