ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reaction of di(isopropyl)aminophosphaethyne 1 with iodomethane or the methyl ester of trifluormethylsulfonic acid (methyl triflate) yields the ionic 1λ3, 3λ3-diphosphetene derivatives + X- (2a: X = I; 2b: X = CF3SO3). On the basis of NMR spectroscopic and X-ray diffraction studies, the cation can be described as a combination of an amino-2-phosphaallylic cation and its methylated derivative.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hc.520050404