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Digitale Medien

A differential technique which is independent of initial conditions for calculating the rate constant of a second-order reaction (1973)

Wen, Walter Y.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 5 (1973), S. 621-627

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Details

ISSN: 0538-8066

Schlagwort(e): Chemistry ; Physical Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: It has been shown that experimental errors of the initial conditions of a second-order reaction can cause erroneous results with the rate constant calculated directly from the differential or integrated rate expression. By means of a computer method, a differential technique has been developed so that precise initial reactant conditions are not necessary for calculating a second-order rate constant if continuous measurements of a single reaction variable are available. The technique has been successfully applied to the data of Kistiakowsky and Lacher on the condensation of acrolein and butadiene.

Zusätzliches Material: 2 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/kin.550050412

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